If 425.0 grams of butene react completely in excess oxygen, how many grams of each product are produced? How many grams would be produced if the percent yield is 67? At STP what would be the volume of the gas produced for this yield?

Respuesta :

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Answers:

A. 1333  g CO₂; 546.0 g H₂O

B. 2200 g CO₂; 370    g H₂O

C.   460 L

Step-by-step explanation:

We know we will need a balanced equation with masses and molar masses, so let’s gather all the information in one place.  

M_r:  56.11                  44.01    18.02

         C₄H₈ + 6O₂ ⟶ 4CO₂ + 4H₂O

m/g:  425.0

A. Theoretical yield of each product

(1) Calculate the moles of C₄H₈

n = 425.0 ×1/56.11

n = 7.574 mol C₄H₈

(2) Calculate the moles of COâ‚‚ and Hâ‚‚O

In each case, the molar ratio is 4 mol product/1 mol C₄H₈.

COâ‚‚ and Hâ‚‚O:

n = 7.574× 4/1

n = 30.30 mol

(3) Calculate the masses of COâ‚‚ and Hâ‚‚O

Mass of CO₂ = 30.30 mol CO₂ × (44.01 g CO₂/1 mol CO₂)

Mass of COâ‚‚ = 1333 g COâ‚‚

Mass of H₂O = 30.30 mol H₂O × (44.01 g H₂O/1 mol H₂O)

Mass of Hâ‚‚O = 546.0 g Hâ‚‚O

B. Actual yield of each product

Mass of CO₂ = 3333 g × 67/100

Mass of COâ‚‚ = 2200 g COâ‚‚

Mass of H₂O = 546.0 g × 67/100

Mass of Hâ‚‚O = 370 g Hâ‚‚O

C. Volume of gas

At STP, COâ‚‚ is a gas, but Hâ‚‚O is a liquid.

Moles of gas = moles of COâ‚‚

If the actual yield is 67 %

Moles of CO₂ = 30.30 mol × 67/100

Moles of COâ‚‚ = 20 mol

STP is 1 bar and 0 °C.

The molar volume at STP is 22.71 L.

∴ V = 201 mol × 22.71 L/1 mol

   V = 460 L